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Give two examples of valency expanded molecule. What is the basic requirement for an element to form valency expanded molecule?

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JU-PHY2nd YearFinalChemistry-IIThe Chemical BondsElectronic theory of valency (Topic Practice)JU-PHY - ⚡ অনলাইন প্রশ্নব্যাংক দেখুন 💥
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Another Explanation (5):

Two examples of valency-expanded molecules are:

  • SF6 (sulfur hexafluoride)
  • PCl5 (phosphorus pentachloride)

The basic requirement for an element to form a valency-expanded molecule is that it must have d orbitals available in its valence shell to accommodate more than eight electrons.