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Explain the Octet rule. Mention its limitations.

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JU-PHY2nd YearFinalChemistry-IIThe Chemical BondsElectronic theory of valency (Topic Practice)JU-PHY - ⚡ অনলাইন প্রশ্নব্যাংক দেখুন 💥
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Another Explanation (5):

The Octet Rule states that atoms tend to gain, lose, or share electrons in order to have eight electrons in their valence shell (outermost electron shell), achieving a stable electron configuration similar to that of a noble gas. This stability is associated with a lower energy state.

Limitations:

  • Incomplete octets: Some elements, particularly those in the second period (like Be and B), are stable with fewer than eight electrons.
  • Expanded octets: Elements in the third period and beyond can have more than eight electrons in their valence shell, forming hypervalent molecules (e.g., PCl5, SF6).
  • Odd-electron molecules: Molecules with an odd number of electrons (e.g., NO) cannot satisfy the octet rule for all atoms.
  • Transition metals: Transition metals often do not follow the octet rule, using d and f orbitals in bonding.